trans-Dibromidobis(triphenylphosphane)platinum(II) chloroform monosolvate
نویسندگان
چکیده
Both the platininum complex and the solvent mol-ecule of the title compound, [PtBr(2)(C(18)H(15)P)(2)]·CHCl(3), are located on a twofold rotation axis. The CH unit and the Cl atoms of the CHCl(3) mol-ecule are disordered over two equally occupied positions. The complex shows a trans square-planar geometry about the Pt atom.
منابع مشابه
trans-Dibromidobis(triphenylphosphine-κP)palladium(II) chloroform monosolvate
The Pd(II) atom in the title compound, [PdBr(2){P(C(6)H(5))(3)}(2)]·CHCl(3), lies on a twofold rotation axis and is coordinated in a distorted square-planar geometry by two P atoms from two triphenyl-phosphine ligands and by two Br atoms in a trans arrangement. The chloro-form solvent mol-ecule is equally disordered about another twofold rotation axis.
متن کامل(4,4′,6,6′-Tetra-tert-butyl-2,2′-{[2-(dimethylamino)ethyl]nitrilobis(methylene)}diphenolato)dioxidomolybdenum(VI) chloroform monosolvate
In the title compound, [Mo(C(34)H(54)N(2)O(2))O(2)]·CHCl(3), the molybdenum(VI) ion exhibits a cis-dioxide distorted octa-hedral geometry. Two anionic phenolate O-atom donors and two neutral N-atom donors of the ligand are trans and cis, respectively. The Mo=O bond lengths and the O=Mo=O bond angle are typical for six-coordinated dioxomolyb-denum(VI) complexes. The Mo-N bond lengths are longer ...
متن کاملCrystal structure of μ-1κC:2(η2)-carbonyl-carbonyl-1κC-chlorido-2κCl-μ-chloridoborylene-1:2κ2 B:B-[1(η5)-pentamethylcyclopentadienyl](tricyclohexylphosphane-2κP)iron(II)platinum(II) benzene monosolvate
In the mol-ecular structure of the dinuclear title compound [η(5)-(C5(CH3)5)(CO)Fe{(μ-BCl)(μ-CO)}PtCl(P(C6H11)3)]·C6H6, the two metal atoms, iron(II) and platinum(II), are bridged by one carbonyl (μ-CO) and one chlorido-borylene ligand (μ-BCl). The Pt(II) atom is additionally bound to a chloride ligand situated trans to the bridging borylene, and a tri-cyclo-hexyl-phosphane ligand (PCy3) trans ...
متن کاملμ-Azido-κ2 N 1:N 1-μ-chlorido-bis[(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ2 C 1,N)palladium(II)] chloroform monosolvate
In the binuclear title complex, [Pd2(C11H13ClN)2Cl(N3)]·CHCl3, each Pd(II) atom has a slightly distorted square-planar geometry being coordinated by a C and an N atom of the 2-chloro-3-dimethyl-amino-1-phenyl-propyl ligand, a bridging Cl atom and an N atom of a bridging end-on azide group. There is a short intra-molecular C-H⋯Cl contact in the complex mol-ecule. In the crystal, the chloro-form ...
متن کاملtrans-Dibromidobis(1-ethyl-3-methylimidazol-2-ylidene)palladium(II)
The title compound, trans-[PdBr(2)(C(6)H(10)N(2))(2)], was synthesized ionothermally in the ionic liquid solvent 1-ethyl-3-methyl-imidazolium bromide. In the crystal, the Pd(II) atoms are square-planarly coordinated to two Br atoms and two neutral (C(6)H(10)N(2)) ligands. The Pd(II) atom is located on an inversion centre.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011